Removal of Cationic Dyes (Crystal Violet) by Using Low-cost Surface as an Ecofriendly Surface
Abstract
This research aimed to study the adsorption properties of the Sodium alginate-g-poly(Acrylic acid-fumaric acid) hydrogel surface on crystal violet dye. Two techniques were used, including [fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM)] to study the surface properties before and after the adsorption process. Several factors such as (equilibrium time, concentration of crystal violet dye, weight of hydrogel, solution of pH, and temperature) were studied. It was found through the results that with increasing the concentration of crystal violet dye, the adsorption efficiency increases, and the removal percentage decreases. On the contrary, by increasing hydrogel's weight, the adsorption efficiency decreases, and the removal percentage increases from (96.12 to 66.33 mg/g), depending on the fullness of the active sites. The removal percentage E% of crystal violet dye using hydrogel surface rise with increased solution pH to reach the maximum pH 6.5 (99.123%). The thermodynamic functions were studied; the reaction was spontaneous and exothermic (ΔΗ° (KJ/mol¯¹) -3.8809). Also, study isotherms and adsorption kinetics were found to fit the Frendlich model (R2 = 0.9875)and the second-order model (R2 = 0.849), respectively.Keywords:
Adsorption, Crystal violet, Isotherm, Kinetic, Removal, ThermodynamicReferences
1. Gouamid M and Bensaci M B. Adsorption Equilibrium, Kinetics and Thermodynamics of Methylene Blue from Aqueous Solutions using Date Palm Leaves. Energy Procedia. 2013; 36: 898-907.
2. Yazidi A. Adsorption of amoxicillin and tetracycline on activated carbon prepared from durian shell in single and binary systems: Experimental study and modeling analysis. Chemical Engineering Journal. 2020;379: 122320.
3. Bader A T, Zaied A M, Aljeboree A M, Alkaim A F. Removal Of Methyl Violet (Mv) From Aqueous Solutions By Adsorption Using Activated Carbon From Pine Husks (Plant Waste Sources). Plant Archives. 2019;19(2):898-901.
4. Nadher DR, Layth SJ. Synthesis of Graphene Oxide/Hydrogel Composites and Their Ability for Efficient Adsorption of Crystal Violet. J. Pharm. Sci. & Res. 2019;11(2):456-463.
5. Moussavi G, Alahabadi A, Yaghmaeian K, Eskandari M. Preparation, characterization and adsorption potential of the NH4Cl-induced activated carbon for the removal of amoxicillin antibiotic from water. Chemical Engineering Journal. 2020; 217:119-128.
6. Aljeboree AM, Abbas NA, Alkaim AF. Activated Carbon (As A Waste Plant Sources)-Clay Micro/Nanocomposite As Effective Adsorbent: Process Optimization For Ultrasound-Assisted Adsorption Removal Of Amoxicillin Drug. Plant Archives. 2019;19(2):915-919.
7. Abbas NK, Layth SJ. Synthesis and Characterization of Poly (CH/AA-co-AM) Composite: Adsorption and Thermodynamic Studies of Benzocaine on from Aqueous Solutions International Journal of Drug Delivery Technology. 2019;9(4):558-562.
8. Basam WM, Nadher DR, Layth SJ, Hayder OJ. Synthesis and characterization of polyacrylamide hydrogel for the controlled release of aspirin. J. Pharm. Sci. & Res. 2018; 10(11): 2850-2854.
9. Mhammed A, Atyaa AA, Radhy ND, Jasim LS. A new adsorption material based GO/PVP/AAc composite hydrogel characterization, study kinetic and thermodynamic to removal Atenolol drug from wast water. IOP Conference Series: Materials Science and Engineering. 2020;928(6):062023.
10. Zaied AM, Ali TB, Aljeboree AM, Alkaim AF. Adsorption And Removal Of Textile Dye (Methylene Blue Mb) From Aqueous Solution By Activated Carbon As A Model (Apricot Stone Source Waste) Of Plant Role In Environmental Enhancement. Plant Archives. 2019;19(2):910-914.
11. Layth SJ, Radhy ND, Hayder OJ. Synthesis and Characterization of Poly (Acryl Amide - Maleic Acid) Hydrogel: Adsorption Kinetics of a Malachite Green from Aqueous Solutions Eurasian Journal of Analytical Chemistry. 2018; 13(1b): em74.
12. Farabi T, SezenKucukcongar M. Removal of methylene blue from aqueous solutions by silica gel supported calix[4]arene cage: Investigation of adsorption properties. European Polymer Journal. 2020;125(15):109540.
13. Aljeboree AM, Alkaim AF. Comparative Removal Of Three Textile Dyes From Aqueous Solutions Byadsorption : As A Model (Corn-Cob Source Waste) Of Plants Role In Environmental Enhancement. Plant Archives. 2019;19(1):1613-1620.
14. Waleed KA, Safaa HG, Nadher DR, Layth SJ. New Approach for Sulfadiazine Toxicity Management using Carboxymethyl Cellulose Grafted Acrylamide Hydrogel. International Journal of Drug Delivery Technology. 2020;10(2):259-264.
15. Safaa HG, Aljeboree MA, Makarim AM, Layth SJ. Synthesis And Characterization OfNTADCIP/P(AA-Co-AM) Composite: Adsorption And Removal Studies Of Drug From Aqueous Solutions Sys Rev Pharm. 2020;11(7):1-6
16. Aljeboree AM. Removal of Vitamin B6 (Pyridoxine) Antibiotics Pharmaceuticals From Aqueous Systems By ZnO. International Journal of Drug Delivery Technology. 2019;9(2):125-129.
17. Aljeboree AM, Alkaim AF. Comparative Removal Of Three Textile Dyes From Aqueous Solutions By Adsorption: As A Model (Corn-Cob Source Waste) Of Plants Role In Environmental Enhancement. Plant Archives. 2019;19(1): 1613-1620.
18. Layth SJ, Aljeboree MA. Removal of Heavy Metals by Using Chitosan/ Poly (Acryl Amide-Acrylic Acid) Hydrogels: Characterization and Kinetic Study. Neuro Quantology. 2021; 19(2): 31-37.
19. Aseel M Aljeboree, Hazim Y Al, Mohammed H S, Alkaim AF. The effect of different parameters on the removal of vitamin B12 drug (as a model biochemical pollutants) by AC/clay. Biochem. Cell. Arch. 2019;19(1):755-759.
20. Saeed UJ, Adnan AK, Saad M, Iftikhar A, Guohua S, Cheng-Meng C, Rashid A. Removal of azo dye from aqueous solution by a low-cost activated carbon prepared from coal: adsorption kinetics, isotherms study, and DFT simulation. Environmental Science and Pollution Research. 2020; 1: https://doi.org/10.1007/s11356-020-11344-4.
21. Aljeboree AM, Alkaim AF. Role Of Plant Wastes As An Ecofriendly For Pollutants (Crystal Violet Dye) Removal From Aqueous Solutions. Plant Archives. 2019;19(2):902-905.
22. Ali MJ, Bassam AJ, Abdulrazzak FH, Alkaim AF, Hussein FH. Synthesis and Characterization of Carbon Nanotubes by Modified Flame Fragments Deposition Method. Asian journal of chemistry. 2017; 29(12): 2804-2808.
23. Kenta S, Suruz M, Kunio O. Low-temperature growth of VO2 films on transparent ZnO/glass and Al-doped ZnO/glass and their optical transition properties. Thin Solid Films. 2018;651(24): 91-96.
24. Mobasherpour I, Salahi E, Pazouki M. Removal of nickel (II) from aqueous solutions by using nano-crystalline calcium hydroxyapatite. Journal of Saudi Chemical Society. 2011; 15(2):105-112.
25. Jain J, Gupta AK, Bhatnagar VK, Suhas A. Utilization of industrial waste products as adosrbents for the removal of dyes. J. Hazard. Mater. B. 2003;101:31-42.
26. Freundlich HW. The Adsorption of cis- and trans-Azobenzene J Am Chem Soc. 1939;61:2228-2230.
27. Nadavala SK, Anesh MP, Madala S, Mansour I. Equilibrium and Kinetic Studies of Biosorptive Removal of 2,4,6-Trichlorophenol from Aqueous Solutions Using Untreated Agro-Waste Pine Cone Biomass. processes. 2019; 1: 22-33.
28. Alipanahpour ED, Ghaedi AM, Asfaram A, Goudarzi A, Hajati S, Soylak M, Shilpi A, Vinod KG. Modeling of quaternary dyes adsorption onto ZnO-NR-AC artificial 3 neural network: Analysis by derivative spectrophotometry Journal of Industrial and Engineering Chemistry. 2015;1:22.
29. Safa AY, Abdulrazzak FH. Enhance the Growth of Multi- walled Carbon Nanotubes from Coal by Catalytic Chemical Flame Deposition. IOP Conf. Series: Materials Science and Engineering. 2019;571:1-3.
30. Namer AH, Layth SJ. Kinetic Study of removal Zinc Oxide Nanoparticles from Aqueous Solutions on synthesized CH-g-P(AAc-co-Am). IOP Conf. Series: Earth and Environmental Science. 2021;790:012064.
Published
Abstract Display: 0 
PDF Downloads: 0 
