Enhanced Removal of Phenylephrine Hydrochloride using Eco-friendly Surface: Optimization, Isotherm, Kinetics, and Regeneration Studies
Abstract
Phenolic compounds are highly toxic pollutants. They are widely used in tanning, dye, chemical, cosmetic and pharmaceutical industries. They come from different sources, like industrial wastewater, gasworks, paper mill, chemical plants, coking factories, pharmaceutical industry, and solid castoff of coal tar. This study used a phenolic Phenylephrine hydrochloride PHCL drug, characterized by a very high toxicity in water. Therefore, a new surface with very high efficiency was prepared to remove this drug from water. The hydrogel surface properties such as fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FESEM) were studied. Two types of Frendelich and Langmuir isotherms were also studied. Through the results, it was found that obeys the Freundlich model. Three models of Kinetic first-order, second-order, and Elcovich models were found through the data to obey a false first-order model.Keywords:
Adsorption, Drug, Hydrogel, Isotherm, Kinetic model, Phenylephrine hydrochlorideReferences
1. Radhi IM, Abdulrazzak FH, Himdan TA. Influence of water in size of Synthesized Carbon Black Nanoparticles from Kerosene by Flame Method. IOP Conf. Series: Materials Science and Engineering. 2019;571.
2. Walter K, Dodds M. Chapter 16 - Responses to Stress, Toxic Chemicals, and Other Pollutants in Aquatic Ecosystems, in Aquatic Ecology. 2020; 453-502.
3. Nupur N, Kriti D, Abhinav S, Rekha S. Supercritical Extraction of Valued Components From Animals Parts. Food Science. 2021;1:doi.org/10.1016/B978-0-08-100596-5.22673-5.
4. Romero F, Sabater S, Font C, Balczar JL, Acua V. Desiccation events change the microbial response to gradients of wastewater effluent pollution. Water Research. 2019;151:371-380.
5. Basam WM, Nader DR, Layth SJ, Hayder OJ. Synthesis and characterization of polyacrylamide hydrogel for the controlled release of aspirin. J. Pharm. Sci. & Res. 2018;10(11): 2850-2854.
6. Ali M. Jassm, Joud B A, Abdulrazzak FH, Alkaim AF, Hussein FH. Synthesis and Characterization of Carbon Nanotubes by Modified Flame Fragments Deposition Method. Asian journal of chemistry. 2017;29(12):2804-2808.
7. Aljeboree AM, Abbas NA. Colorimetric determination of Amoxicillin using 4-Aminoantipyrine and the effects of different parameters. Journal of Physics: Conference Series. 2019;12(5): 052067.
8. Danner MC, Robertson A, Behrends V, Reiss J. Antibiotic pollution in surface fresh waters: Occurrence and effects. Science of The Total Environment. 2019;664:793-804.
9. Quesada HB, Baptista A, Takaoka A, Cusioli L, Fernando S, Daiana D, Oliveira B, Charleston B. Surface water pollution by pharmaceuticals and an alternative of removal by low-cost adsorbents: A review. Chemosphere. 2019;222:766-780.
10. Abdulrazzak FH.Enhance photocatalytic Activity of TiO2 by Carbon Nanotubes. International Journal of ChemTech Research. 2016;9(3):431-443
11. Kumar R, Sarmah AK, Padhye LP. Fate of pharmaceuticals and personal care products in a wastewater treatment plant with parallel secondary wastewater treatment train. Journal of Environmental Management. 2019;233:649-659.
12. Turk S. Surface functionalised adsorbent for emerging pharmaceutical removal: Adsorption performance and mechanisms. Process Safety and Environmental Protection. 2019; 125:50-63.
13. Liqaa HA, Abbas R, Aljeboree AM, Abdulrazzak FH, Hussein FH, Alkaim AF. Role of Semiconductors (Zinc Oxide as a Model) for Removal of Pharmaceutical Tetracycline (TCs) from Aqueous Solutions in the Presence of Selective Light. International Journal of Recent Technology and Engineering (IJRTE). 2019;8(2S3): DOI: 10.35940/ijrte.B1270.0782S319.
14. Aljeboree AM, Alshirifi AN. Oxidative coupling of Amoxicillin using 4-Aminoantipyrine: Stability and higher sensitivity. Journal of Physics: Conference Series. 2019;1294(5): 052001.
15. Salem Y. Application of derivative emission fluorescence spectroscopy for determination of ibuprofen and phenylephrine simultaneously in tablets and biological fluids. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2019;210:387-397.
16. Águila-Carrasco A. Effect of phenylephrine on static and dynamic accommodation. Journal of Optometry. 2019;12(1): 30-37.
17. Zhang Z, Zhang Y, Gerk PM. Preparation of phenylephrine 3-O-sulfate as the major in vivo metabolite of phenylephrine to facilitate its pharmacokinetic and metabolism studies. Journal of Pharmacological and Toxicological Methods. 2019;95:66-69.
18. Jasim LS, Radhy ND, Jamel HO. Synthesis and characterization of poly (acryl amide-Maleic acid) hydrogel: Adsorption kinetics of a malachite green from aqueous solutions. Eurasian Journal of Analytical Chemistry. 2018;13(1): 10.29333/ejac/101789
19. Maximino MD. Synergy in the interaction of amoxicillin and methylene blue with dipalmitoyl phosphatidyl choline (DPPC) monolayers. Applied Surface Science. 2019; 476:493-500.
20. Yaqo EA, Anaee RA, Abdulmajeed MH, Tomi IHR, Kadhim MM. Electrochemical, morphological and theoretical studies of an oxadiazole derivative as an anti-corrosive agent for kerosene reservoirs in Iraqi refineries ;Chemical Papers. 2020; 74 (6):1739-1757.
21. Al-Jbouri AMS, Abood FM, Hindi NKK, Alkaim AF. Evaluation of antimicrobial activity of the aquatic extract against bacterial isolates from periodontitis in Babylon Province, Iraq; Biochemical and Cellular Archives. 2018;18:1345-1350.
22. Al-Duhaidahawi DL, Jabir MS, Al-Amiery AA, Moneim AEA, Alkaim AF, Kadhum AAH. Novel antioxidants compounds derived from isatine Biochemical and Cellular Archives. 2018;18 (1):709-713.
23. Abdoon FM, Yahyaa SY. Validated spectrophotometric approach for determination of salbutamol sulfate in pure and pharmaceutical dosage forms using oxidative coupling reaction. Journal of King Saud University-Science, 2018. 1: https://doi.org/10.1016/j.jksus.2018.;11.002.
24. Aljeboree AM, Alkaim FA. Comparative Removal Of Three Textile Dyes From Aqueous Solutions By Adsorption: As A Model (Corn-Cob Source Waste) Of Plants Role In Environmental Enhancement. Plant Archives. 2019;19(1):1613-1620.
25. Bader AT, Zaied AM, Aljeboree AM, Alkaim AF. Removal of Methyl Violet (MV) From Aqueous Solutions By Adsorption Using Activated Carbon From Pine Husks (Plant Waste Sources). Plant Archives. 2019;19(2): 898-901.
26. Alkaim AF, Alqaragully MB. Adsorption of Basic Yellow Dye From Aqueous Solutions By Activated Carbon Derived From Waste Apricot Stones (ASAC): Equilibrium, And Thermodynamic Aspects Int. J. Chem. Sci. 2013; 11(2): 797-814.
27. Aljeboree AM, Abbas AS. Removal of Pharmaceutical (Paracetamol) by using CNT/ TiO2 Nanoparticles. Journal of Global Pharma Technology. 2019; 11(01): 199-205.
28. Mhammed A, Atyaa AI, Radhy ND, Jasim LS. A new adsorption material based GO/PVP/AAc composite hydrogel characterization, study kinetic and thermodynamic to removal Atenolol drug from wast water. IOP Conference Series: Materials Science and Engineering. 2020;928(6):062023.
29. Layth SJ, Aljeboree MA. Removal of Heavy Metals by Using Chitosan/Poly (Acryl Amide-Acrylic Acid) Hydrogels: Characterization and Kinetic Study. Neuro Quantology. 2021;19(2): 31-37.
30. Alidadi MD, Mojtaba D, Fateme B, Farideh J, Ahmad H. Enhanced removal of tetracycline using modified sawdust:Optimization, isotherm, kinetics, and regeneration studiesHosein Process Safety and Environmental Protection. 2018;117: 51-60.
31. Abbas NK, Layth SJ. Synthesis and Characterization of Poly (CH/AA-co-AM) Composite: Adsorption and Thermodynamic Studies of Benzocaine on from Aqueous Solutions International Journal of Drug Delivery Technology. 2019;9(4):558-562.
32. Aljeboree AM. Spectrophotometric and Colorimetric Determination of Pharmaceutical by Oxidative Coupling Reaction: A Review. Sys Rev Pharm. 2020;11(4): 609-615.
33. Ho YS, McKay G. Orption of dye from aqueous solution by peat. S Chem. Eng. J, 1998;70:115.
34. Waleed KA, Safaa HG, Makarim AM, Layth SJ. Adsorptive Removal of Doxycycline From Aqueous Solution Using Graphene Oxide/Hydrogel Composite. International Journal of Applied Pharmaceutics. 2020;12(6): 100-106.
35. Waleed KA, Safaa HG, Nadher DR, Layth SJ. New Approach for Sulfadiazine Toxicity Management using Carboxymethyl Cellulose Grafted Acrylamide Hydrogel. International Journal of Drug Delivery Technology. 2020;10(2): 259-264.
Published
Abstract Display: 0
PDF Downloads: 0